The Grignard Reaction is the addition of an organomagnesium halide (Grignard reagent) to a ketone or aldehyde, to form a tertiary or secondary alcohol, respectively.
Reactions of Grignard reagents with aldehydes and ketones These are reactions of the carbon-oxygen double bond, and so aldehydes and ketones react in exactly the same way - all that changes are the groups that happen to be attached to the carbon-oxygen double bond. An acid halide (X) reacts with excess of grignard reagent. The product (Y) can be:

The … Any excess Grignard reagent must be quenched before disposal.
Grignard reagents can also decompose by other pathways or dimerize under the reaction conditions rather than undergoing the reaction desired, and one may find that it is necessary to use excess Grignard reagent in those circumstances. A Grignard reagent is prepared in excess relative to an aldehyde, because you seldom get a 100 % yield of the reagent.


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